Unimolecular Solvolysis

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…the amount of hydroxide is equivalent to ten percent of the total amount of tert-butyl chloride. Solvolysis begins at the time of mixing and proceeds to give Tert-butyl alcohol and hydronium ion at a characteristic rate. If bromphenol blue indicator is added, when the hydronium ion has neutralized the sodium hydroxide, the indicator changes from blue to yellow and the time required for this change represents ten percent of the time for the total reaction.